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Spider-Man: The Animated Series Season 4 Episode 5

While settling in to her new role as a hero, the Black Cat is captured by Allistair Smythe, now working for Silvermane, who is trapped in the body of a baby. Smythe delivers Spidey an ultimatum: capture the Scorpion or the Vulture within 24 hours or the Black Cat dies…

Episode Title: Partners in Danger: Partners

Air Date: 1997-05-03